Giles, M. D.; Liu, S.; Emanuel, R.; Gibb, B.; Grayson, S. Divergent Dendronization of Deep-Cavity Cavitands to Tune Host Solubility. Israel Journal of Chemistry 2009, 49, 31-40.
Abstract
Abstract Resorcinarene-based deep-cavity cavitands (DCCs) are useful components in supramolecular chemistry because their extended cavity enables the encapsulation of relatively large guests. To provide H2O solubility, they have been modified with hydroxyl functionalized dendrons. This has been carried out by the divergent dendronization of aliphatic poly(ester) dendrons through the third dendritic generation. The resultant macromolecule demonstrated the desired H2O solubility.
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